不銹(xiu)鋼(gang)的(de)爐(lu)中釬焊一般是在某種(zhong)保護性氣(qi)氛下或真空中進行,保護氣(qi)氛有氫氣(qi)、分解氨(an)和(he)氬氣(qi)。
干燥的氫氣或分解氨常用做爐中釬(han)焊不銹鋼時的還原性保護氣氛,它們可還原不銹鋼(gang)表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。
使(shi)(shi)用(yong)氫(qing)(qing)氣(qi)(qi)或(huo)(huo)分(fen)解(jie)氨(an)作保護(hu)氣(qi)(qi)氛的(de)好處是(shi):可實現釬焊(han)爐的(de)連(lian)續工作,便(bian)于大(da)批量生產(chan);釬焊(han)過程中(zhong)不(bu)需使(shi)(shi)用(yong)釬劑,且焊(han)后(hou)工件(jian)光亮,無需任何焊(han)后(hou)工件(jian)表(biao)面清理工作;可配合(he)選(xuan)用(yong)的(de)釬料品種多;在批量生產(chan)條件(jian)下焊(han)接(jie)成本低。但是(shi)使(shi)(shi)用(yong)氫(qing)(qing)氣(qi)(qi)或(huo)(huo)分(fen)解(jie)氨(an)作保護(hu)氣(qi)(qi)氛時(shi)(shi)要注(zhu)意生產(chan)安全,當(dang)空氣(qi)(qi)中(zhong)混有4%~74%的(de)氫(qing)(qing)氣(qi)(qi)或(huo)(huo)12.5%~27%氨(an)氣(qi)(qi)時(shi)(shi),會因燃燒(shao)而產(chan)生爆炸。
作為(wei)惰性(xing)氣(qi)(qi)(qi)體,氬氣(qi)(qi)(qi)可用(yong)作爐(lu)中(zhong)(zhong)釬(han)(han)焊不銹(xiu)鋼(gang)時的保護氣(qi)(qi)(qi)氛。與氫氣(qi)(qi)(qi)和分(fen)解氨不同,氬氣(qi)(qi)(qi)不具有還(huan)原性(xing),只是利用(yong)其(qi)惰性(xing)保護不銹(xiu)鋼(gang)表面(mian)在(zai)釬(han)(han)焊過程中(zhong)(zhong)不氧化,所以不銹(xiu)鋼(gang)進爐(lu)釬(han)(han)焊前(qian)必須徹(che)底清除其(qi)表面(mian)的氧化膜(mo),并且一(yi)般要求氬氣(qi)(qi)(qi)的露點低于-40℃。
使用(yong)氬氣(qi)(qi)作保護(hu)氣(qi)(qi)氛(fen)一般(ban)是(shi)因為以下某種(zhong)或多(duo)種(zhong)原因:①. 可采用(yong)含(han)高蒸汽壓元素的釬(han)(han),如錳基釬(han)(han)料(liao)或含(han)錳較多(duo)的釬(han)(han)料(liao);②. 單件或小批量釬(han)(han)焊(han)時,設備成本低;③. 不(bu)銹(xiu)鋼與異種(zhong)材釬(han)(han)焊(han)時避免(mian)某些材料(liao)與爐內(nei)氣(qi)(qi)氛(fen)的反(fan)應,如在含(han)氫(qing)氣(qi)(qi)氛(fen)中釬(han)(han)焊(han)連(lian)接不(bu)銹(xiu)鋼與鈦合金時,鈦金吸氫(qing)并(bing)與氫(qing)反(fan)應;④. 生產(chan)過(guo)程安全。
使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過
程中要隨時(shi)注意容器(qi)內(nei)的壓力,當容器(qi)內(nei)壓力超過大(da)氣(qi)(qi)壓較多時(shi)應隨時(shi)放(fang)出一(yi)些氣(qi)(qi)體,以保證(zheng)容器(qi)完好和生(sheng)產(chan)安全(quan)。使(shi)(shi)用特制的容器(qi)還有(you)另一(yi)個便利(li):當使(shi)(shi)用未經凈(jing)化的普通(tong)(tong)瓶裝(zhuang)氬氣(qi)(qi)時(shi),可向釬(han)焊爐(lu)內(nei)通(tong)(tong)入少許BF3氣(qi)(qi)體釬(han)劑,或(huo)加(jia)入少許氟(fu)硼(peng)酸鉀,氟(fu)硼(peng)酸鉀在(zai)(zai)800~900℃分解產(chan)生(sheng)BF3.BF3可以去除金屬(shu)表面的氧化物,促進釬(han)料的潤濕。氣(qi)(qi)體釬(han)劑的使(shi)(shi)用濃度一(yi)般控制在(zai)(zai)0.1%~0.001%(體積(ji)分數(shu)),避免焊后形成(cheng)殘渣。氟(fu)化物對人(ren)體有(you)害,要注意工作場地(di)的通(tong)(tong)風。
在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。
在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。
爐中釬(han)(han)(han)(han)(han)焊(han)(han)(han)時(shi)(shi)(shi)影響釬(han)(han)(han)(han)(han)焊(han)(han)(han)接(jie)頭性(xing)能(neng),特別是力學性(xing)能(neng)的(de)主要工(gong)藝參(can)數(shu)包釬(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)、保(bao)(bao)溫(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)。釬(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)一(yi)般選擇在(zai)(zai)(zai)(zai)釬(han)(han)(han)(han)(han)料(liao)液相(xiang)線溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)以上50~100℃,保(bao)(bao)溫(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)在(zai)(zai)(zai)(zai)5~10min.當(dang)工(gong)件(jian)較(jiao)大時(shi)(shi)(shi),可在(zai)(zai)(zai)(zai)升溫(wen)(wen)(wen)(wen)過程中釬(han)(han)(han)(han)(han)料(liao)固(gu)相(xiang)線溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)以下(xia)(xia)某溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)保(bao)(bao)溫(wen)(wen)(wen)(wen)一(yi)段時(shi)(shi)(shi)間(jian)(jian),確保(bao)(bao)工(gong)件(jian)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)均勻(yun)。使(shi)用鎳基(ji)釬(han)(han)(han)(han)(han)料(liao)時(shi)(shi)(shi),除(chu)了釬(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)保(bao)(bao)溫(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)外,釬(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙(xi)也是接(jie)頭強(qiang)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)塑(su)性(xing)的(de)決定(ding)因素(su)之一(yi)。圖3-5、圖3-6顯示了三種(zhong)鎳基(ji)釬(han)(han)(han)(han)(han)料(liao)釬(han)(han)(han)(han)(han)焊(han)(han)(han)不(bu)銹鋼時(shi)(shi)(shi)釬(han)(han)(han)(han)(han)焊(han)(han)(han)接(jie)頭強(qiang)度(du)(du)(du)(du)(du)(du)與(yu)釬(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙(xi)的(de)關系。為(wei)(wei)降低釬(han)(han)(han)(han)(han)料(liao)的(de)熔點,鎳基(ji)釬(han)(han)(han)(han)(han)料(liao)中含(han)有較(jiao)多(duo)的(de)硼(peng)、硅(gui)(gui)、磷(lin),它們在(zai)(zai)(zai)(zai)釬(han)(han)(han)(han)(han)料(liao)組織(zhi)中以脆(cui)性(xing)的(de)硼(peng)化物(wu)、硅(gui)(gui)化物(wu)、磷(lin)化物(wu)形式(shi)存在(zai)(zai)(zai)(zai)。釬(han)(han)(han)(han)(han)焊(han)(han)(han)時(shi)(shi)(shi)在(zai)(zai)(zai)(zai)一(yi)定(ding)的(de)釬(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)保(bao)(bao)溫(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)下(xia)(xia),當(dang)釬(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙(xi)小(xiao)于某一(yi)數(shu)值(zhi),硼(peng)、硅(gui)(gui)、磷(lin)向(xiang)母(mu)(mu)材擴散充分,凝固(gu)后釬(han)(han)(han)(han)(han)縫(feng)(feng)組織(zhi)為(wei)(wei)鎳基(ji)固(gu)溶體,釬(han)(han)(han)(han)(han)縫(feng)(feng)強(qiang)度(du)(du)(du)(du)(du)(du)高、塑(su)性(xing)好,此數(shu)值(zhi)稱作(zuo)該釬(han)(han)(han)(han)(han)料(liao)在(zai)(zai)(zai)(zai)此釬(han)(han)(han)(han)(han)焊(han)(han)(han)溫(wen)(wen)(wen)(wen)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)保(bao)(bao)溫(wen)(wen)(wen)(wen)時(shi)(shi)(shi)間(jian)(jian)下(xia)(xia)的(de)最(zui)大釬(han)(han)(han)(han)(han)焊(han)(han)(han)間(jian)(jian)隙(xi)。當(dang)釬(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙(xi)超過最(zui)大間(jian)(jian)隙(xi),釬(han)(han)(han)(han)(han)縫(feng)(feng)中硼(peng)、硅(gui)(gui)、磷(lin)向(xiang)母(mu)(mu)材擴散不(bu)充分,釬(han)(han)(han)(han)(han)縫(feng)(feng)中會存在(zai)(zai)(zai)(zai)脆(cui)性(xing)化合物(wu),釬(han)(han)(han)(han)(han)縫(feng)(feng)的(de)強(qiang)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)塑(su)性(xing)都會下(xia)(xia)降。而且在(zai)(zai)(zai)(zai)一(yi)定(ding)范圍內,釬(han)(han)(han)(han)(han)縫(feng)(feng)越寬,釬(han)(han)(han)(han)(han)縫(feng)(feng)中脆(cui)性(xing)相(xiang)越多(duo),接(jie)頭的(de)強(qiang)度(du)(du)(du)(du)(du)(du)和(he)(he)(he)塑(su)性(xing)越低。
在釬(han)(han)(han)焊(han)實際部(bu)件(jian)時(shi),有時(shi)部(bu)件(jian)加工精度(du)或裝配精度(du)很(hen)難保證釬(han)(han)(han)縫間(jian)(jian)隙很(hen)小(xiao),適當(dang)地提高釬(han)(han)(han)焊(han)溫(wen)度(du)或延長保溫(wen)時(shi)間(jian)(jian)可增大(da)(da)最大(da)(da)釬(han)(han)(han)焊(han)間(jian)(jian)隙,見圖3-7。當(dang)在高溫(wen)下長時(shi)間(jian)(jian)保溫(wen)造成母(mu)(mu)材(cai)(cai)晶粒(li)過(guo)分長大(da)(da)或釬(han)(han)(han)料對(dui)母(mu)(mu)材(cai)(cai)溶蝕過(guo)度(du)時(shi),也(ye)可在焊(han)后(hou)接頭冷(leng)卻到某一較低(di)溫(wen)度(du)保溫(wen),通過(guo)擴散消除釬(han)(han)(han)縫中的(de)脆(cui)性相而增大(da)(da)最大(da)(da)釬(han)(han)(han)焊(han)間(jian)(jian)隙,見圖3-8。但由于磷(lin)原(yuan)子較大(da)(da),向母(mu)(mu)材(cai)(cai)中擴散困難,這(zhe)些措施對(dui)Ni-Cr-P和Ni-P這(zhe)類釬(han)(han)(han)料作用不大(da)(da)。
爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。